Aircraft air supply and contaminant detection system

ABSTRACT

An aircraft pressurized air system and method is disclosed. The system includes a compressor that receives and compresses outside air, and an air cycle machine that receives compressed air from the compressor and directs conditioned air to an aircraft pressurized zone. The system also includes a contaminant sensor disposed along an air flow path between the compressor and the aircraft pressurized zone, comprising an optical guide, a metal organic framework on an exterior surface of the optical guide in operative fluid communication with air from the air flow path, a light source in communication with the optical guide at a first end of the optical guide, and a light detector in communication with the optical guide at a second end of the optical guide.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a Division of U.S. application Ser. No. 16/028,999filed Jul. 6, 2018, the disclosure of which is incorporated herein byreference in its entirety.

BACKGROUND

This disclosure relates to aircraft and on-board air supply systems, andmore particularly to an on-board air delivery system with contaminantdetection

Aircraft equipped to fly at elevations above 10,000 feet can include anair supply system that supplies pressurized air to the aircraft cabin.Such systems generally draw a bleed of air from a compressor section ofa gas turbine engine used for propulsion as a source of pressurized air,but can also utilize compressed air from other sources such as anelectrically-powered compressor. The compressed air supply can besubject to further conditioning such as in an air cycle machine in whichthe compressed air can be cooled, subjected to one or more compressionand expansion steps by turbine and compressor blades on a shared rotarypower connection, and dried before delivery to a cabin air recirculationloop. As with any occupied enclosed conditioned air space, it isdesirable to maintain an acceptable air quality, and air treatmentprocesses such as ozone removal and various types of filtration or otherair quality treatments have been used or proposed. However, testing forcontaminants can be challenging in an aircraft environment whereconditions can be adverse and performance specifications can bedemanding.

BRIEF DESCRIPTION

A method of testing for tricresyl phosphate is disclosed. According tothe method, light is directed from a light source to a light detector. Atest gas is contacted with a metal organic framework on an exteriorsurface of an optical guide in communication with the light between thelight source and the light detector, and a change is detected in lightintensity or spectral properties of light received by the light detectorcaused by adsorption of tricresyl phosphate by the metal organicframework.

In any of the above embodiments, the optical guide can comprise a fiberoptic element including a core comprising an optical material with afirst refractive index, said metal organic framework on a first exteriorsurface portion of the core, and a cladding optically coupled to asecond exterior surface portion of the core, said cladding comprising anoptical material with a second refractive index lower than the firstrefractive index and configured to reflect light from the core at aninterface between the core and the cladding.

In any one or combination of the foregoing embodiments, furthercomprising a filament, the first exterior surface portion can bedisposed at a central portion along a length of the filament, and thecladding disposed on each side of the central portion along the lengthof the filament.

In any one or combination of the foregoing embodiments, the metalorganic framework can include pore sizes greater than a molecularkinetic diameter of the tricresyl phosphate.

In any one or combination of the foregoing embodiments, the metalorganic framework can include functional groups interactive withtricresyl phosphate.

In any one or combination of the foregoing embodiments, the metalorganic framework can include pores larger than 1.5 nm.

In any one or combination of the foregoing embodiments, the metalorganic framework can include polar functional groups.

In any one or combination of the foregoing embodiments, the system canfurther comprise a heat source in controllable thermal communicationwith the metal organic framework for regeneration.

In any one or combination of the foregoing embodiments, the system canfurther comprise a controller configured to detect a contaminant basedon output from the light detector, and to generate a response thereto.

In any one or combination of the foregoing embodiments, the method caninclude, or the response generated by the controller can be selectedfrom: providing a system alarm to the presence of the contaminant oractivating an air contaminant removal protocol.

In any one or combination of the foregoing embodiments, the method caninclude, or the response generated by the controller can includeregenerating the metal organic framework with heated air.

BRIEF DESCRIPTION OF THE DRAWINGS

Subject matter of this disclosure is particularly pointed out anddistinctly claimed in the claims at the conclusion of the specification.The foregoing and other features, and advantages of the presentdisclosure are apparent from the following detailed description taken inconjunction with the accompanying drawings in which:

FIG. 1A is a schematic illustration of an aircraft that can incorporatevarious embodiments of the present disclosure;

FIG. 1B is a schematic illustration of a bay section of the aircraft ofFIG. 1A;

FIG. 2 is a schematic depiction of an example embodiment of an aircraftair cycle environmental conditioning system;

FIG. 3 is a schematic depiction of a contaminant sensor.

DETAILED DESCRIPTION

As shown in FIGS. 1A-1B, an aircraft includes an aircraft body 101,which can include one or more bays 103 beneath a center wing box. Thebay 103 can contain and/or support one or more components of theaircraft 101. For example, in some configurations, the aircraft caninclude environmental control systems and/or fuel inerting systemswithin the bay 103. As shown in FIG. 1B, the bay 103 includes bay doors105 that enable installation and access to one or more components (e.g.,environmental control systems, fuel inerting systems, etc.). Duringoperation of environmental control systems and/or fuel inerting systemsof the aircraft, air that is external to the aircraft can flow into oneor more ram air inlets 107. The outside air may then be directed tovarious system components (e.g., environmental conditioning system (ECS)heat exchangers) within the aircraft. Some air may be exhausted throughone or more ram air exhaust outlets 109.

Also shown in FIG. 1A, the aircraft includes one or more engines 111.The engines 111 are typically mounted on wings of the aircraft and areconnected to fuel tanks (not shown) in the wings, but may be located atother locations depending on the specific aircraft configuration. Insome aircraft configurations, air can be bled from the engines 111 andsupplied to environmental control systems and/or fuel inerting systems,as will be appreciated by those of skill in the art.

An aircraft environmental control system, also referred to as an ECS orECS pack, can include customary components for air cycle coolingsystems, including heat exchangers, compressors (e.g., turbine-bladecompressors), turbines, and heat exchanger/water removal units. Aircycle cooling systems can be based on three-wheel architecture (a fan, acompressor, and a turbine) or four-wheel architecture (a fan, acompressor, and two turbines). In some embodiments, the ECS pack coolsbleed air in a ram air heat exchanger, partially re-compresses it in aturbine-powered compressor, cools the partially re-compressed air in asecond pass through the ram air heat exchanger, expands and furthercools the air flow and removes water with a turbine in a flow loop witha heat exchanger water removal unit, and, in the case of a four-wheelarchitecture further expands and cools the air in a second turbine.

An example embodiment of on-board air cycle cooling system 140 isschematically shown in FIG. 2. Air cycle cooling system depicts aso-called “four-wheel” system, referring to the four rotating devices (aram air fan, one compressor, and two turbines), but “three-wheel”systems having only a single turbine are also contemplated. As shown inFIG. 2, compressed air 212 from a compressed air source (not shown) suchas a pre-cooled turbine engine bleed, an APU bleed, or anelectrically-powered compressor is delivered through control valve 214.From there, the compressed air is directed to a heat exchanger 215 (alsoreferred to in the art as a primary heat exchanger) where it rejectsheat to ambient air flowing through or across a heat absorption side ofheat exchanger 215. Cooled compressed air is discharged from heatexchanger 215 to compressor 220. A portion of the air going to heatexchanger 215 can be controllably diverted through conduit 217 andcontrol/expansion valve 219 to mix with the outlet of turbine 244 andcontrol the temperature of the conditioned air exiting the system.Compressor 220 compresses its portion of the air from the heat exchanger215, which also results in heating of the air. The further compressedair is discharged from compressor 220 through conduit 224 to heatexchanger 226 (also referred to in the art as a secondary heatexchanger) where it rejects heat to ambient air flowing through oracross a heat absorption side of heat exchanger 226.

The ambient air 213 flowing through or across the heat absorption sidesof heat exchangers 215 and 226 can be a ram air flow from aforward-facing surface of the aircraft. In conditions under whichinsufficient airflow is generated by the forward motion of the aircraftfor operation of the heat exchangers 215, 226, the air flow can beassisted by operation of fan 228. Check/bypass valve 229 allows forbypass of the fan 228 when ram air flow is sufficient for the needs ofthe heat exchangers 215 and 226. Heat exchangers 215 and 226 can share aflow path for the ambient cooling air, and can be integrated into asingle unit with heat exchanger 215 sometimes referred to as a primaryheat exchanger and heat exchanger 226 sometimes referred to as asecondary heat exchanger. Cooled air discharged from heat exchanger 226is delivered through conduit 232 to a heat rejection side of heatexchanger 230. In the heat rejection side of heat exchanger 230, the airis further cooled to a temperature at or below the dew point of the airand flows into water removal unit 235 where liquid water 236 condensedfrom the air is removed. The dehumidified air flows through a heatabsorption side of heat exchanger 230 where it is re-heated before beingdelivered through conduit 238 to turbine 240, where work is extracted asthe air is expanded and cooled by turbine 240. A portion of the airgoing to turbine 240 can be diverted by valve 241 if needed to allow thetemperature of the air at the inlet to the heat absorption side of heatexchanger 230 to be above freezing. The cooled expanded air dischargedfrom the turbine 240 is delivered through conduit 242 to a heatabsorption side of heat exchanger 230 where it along with thedehumidified air discharged from water collection unit 235 providescooling needed to condense water vapor from air on the heat rejectionside of heat exchanger 230. The air streams on the heat absorption sideof the heat exchanger 230 are thus reheated. Heat exchanger 230 is alsosometimes referred to as a condenser/reheater, and can be integratedwith water removal unit 235 in a single unit. The reheated air fromconduit 242 exiting from the heat absorption side of heat exchanger 230flows through conduit 243 to turbine 244, where it is expanded andcooled, and then discharged from the system 140 through conduit 245 tomix manifold 250 where it is mixed with recirculating air 252 from thecabin or other pressurized zones before being discharged to back to theaircraft cabin or other pressurized zones of the aircraft. Theenvironment air conditioning system 140 also includes a power transferpath 247 such as a rotating shaft that transfers power to the compressor220 and fan 228 from work extracted by turbines 240 and 244.

As mentioned above, this disclosure includes a contaminant sensordisposed on an air flow path between a source of compressed air andpressurized zones of the aircraft such as the cabin, cockpit, cargohold, and some equipment bays. Example locations of a contaminant sensorcan include the ECS conduit 245, the mix manifold 250, or any portion ofa looped flow path for recirculating cabin air 252.

An example embodiment of a contaminant sensor assembly 300 isschematically shown in FIG. 3. As shown in FIG. 3, an optical guide inthe form of a fiber optic element shown in a cross-sectional view with afiber optic element core 302 and a fiber optic element cladding 304around the core 302. The core and cladding can be made of various typesof glass or plastic with high transmissivity and appropriate refractiveindices to guide light within the core axially along the length of thefiber. This is accomplished with a refractive index differential at theinterface along which the core is optically coupled to the cladding suchthat light transmitting through the core that is incident on theinterface totally reflected back into the core according to Snell's Law.This phenomenon is known as total internal reflection, and is the basisfor fiber optic technology, camera and binocular prisms, automotivewindshield rain sensors, and numerous other technologies. A portion ofthe fiber optic element has a layer comprising a metal organic framework(MOF) 306 instead of cladding on the surface of the core 302.

Metal organic framework materials are well-known in the art, andcomprise metal ions or clusters of metal ions coordinated to organicligands to form one-, two- or three-dimensional structures. Ametal-organic framework can be characterized as a coordination networkwith organic ligands containing voids. The coordination network can becharacterized as a coordination compound extending, through repeatingcoordination entities, in one dimension, but with cross-links betweentwo or more individual chains, loops, or spiro-links, or a coordinationcompound extending through repeating coordination entities in two orthree dimensions. Coordination compounds can include coordinationpolymers with repeating coordination entities extending in one, two, orthree dimensions. Examples of organic ligands include but are notlimited to bidentate carboxylates (e.g., oxalic acid, succinic acid,phthalic acid isomers, etc.), tridentate carboxylates (e.g., citricacid, trimesic acid), azoles (e.g., 1,2,3-triazole), as well as otherknown organic ligands. Metal organic frameworks are further described byBatten, S R; Champness, N R; Chen, X-M; Garcia-Martinez, J; Kitagawa, S;Öhrstrom, L; O'Keeffe, M; Suh, M P; Reedijk, J (2013). “Terminology ofmetal-organic frameworks and coordination polymers (IUPACRecommendations 2013)”, Pure and Applied Chemistry. 85 (8): 1715.doi:10.1351/PAC-REC-12-11-2, the disclosure of which is incorporatedherein by reference in its entirety.

A wide variety of metals can be included in a metal organic framework.In some embodiments, the metal organic framework comprises a transitionmetal, including but not limited to any of the transition metalsdescribed above with respect to transition metal oxide adsorbents.Examples of metals that can be included in the metal organic frameworkinclude Cu, Mg, Cr, Al, Mn, Co, Zr Zn. Lanthanide metals can include Ln,Eu, Ce, Er. Examples of specific metal organic framework materialsinclude UIO-66 Zr-bdc, UiO-66-NH₂ ({Zr(bdc-NH₂)₂} with(bdc-NH₂)=2-amino-1,4-benzenedicarboxylate)), UIO-67 (Zr-bpdc) withbpdc=biphenyl-4,4′-dicarboxylic acid), MIL-101 ([Cr₃(O)X(bdc)₃(H₂O)₂](X=OH or F) with bdc=1,4-benzene dicarboxylate), NU-1000({Zr₆(μ₃-OH)₈(—OH)₈(TBAPy)₂ withTABAPy=1,3,6,8,-tetrakis(p-benzoic-acid)pyrene)), PCN-777({[Zr₆(O)₄(OH)₁₀(H₂O)₆(TATB)₂ withTATB=4,4′,4″-s-triazine-2,4,6-triyl-tribenzoate), MOF-808Zr₆O₄(OH)₄(BTC)₂(HCOO)₆ with BTC=1,3,5-benzenetricarboxylate), MOF-200and MOF-210 [Zn₄O(BBC)₂ and (Zn₄O)₃(BTE)₄(BPDC)₃, respectively;BBC=4,4′,4″-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate;BTE=4,4′,4″-(benzene-1,3,5-triyl-tris(ethyne-2,1-diyl)) tribenzoate;BPDC=biphenyl-4,4′-dicarboxylate], MOF-177 [Zn4O(BTB)2;BTB=4,4′,4″-benzene1,3,5-triyl-tribenzoate], [MOF-399, Cu3(BBC)2] withBBC3-=4,4′,4″-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate.MOF's can be synthesized by hydrothermal or solvothermal techniques,where crystals are slowly grown from a hot solution. Templating for theMOF structure can be provided by a secondary building unit (SBU) and theorganic ligands. Alternate synthesis techniques are also available, suchas chemical vapor deposition, in which metal oxide precursor layers aredeposited followed by exposure of the precursor layers to sublimedligand molecules to impart a phase transformation to the MOF crystallattice.

In some embodiments, the MOF 306 can be configured to promote absorptionor adsorption of target contaminant(s). For example, tricresyl phosphateis commonly used as an anti-wear or anti-corrosion additive in hydraulicfluids used on aircraft. Tricresyl phosphate is toxic and has a lowvapor pressure, which can make it a problematic contaminant for aircraftpressurized air, even at low concentrations. In some embodiments, theMOF 306 can be configured to deter absorption or adsorption of potentialcross-contaminants (i.e., compounds that could produce a false positive)by the MOF 306. For example, the MOF can include functional groupsappended to metal or organic portions of the framework that can attractor otherwise interact the contaminant(s). The MOF can also be configuredwith a porosity adapted for adsorption of the contaminant(s). In thecase of testing for TCP, the pore size of the MOF 306 should be largerthan at least 1.5 nm, as the TCP molecule kinetic diameter is largerthan 1.5 nm. In some embodiments, the MOF can include pore sizes from1.5 nm to 4 nm. Polar groups can be included in the MOF 306 to attractor otherwise interact with polar contaminants such as tricresylphosphate. Examples of polar substituent groups that can be included inthe MOF 306 can include hydroxyl, carbonyl, carboxyl, amino. In someembodiments, the MOF 306 can be immobilized in a polymer matrix in orderto increase the sensitivity of the target analyte. In some embodiments,metal oxides (e.g., zinc oxide, iron oxide, titania, vanadium oxide) canbe incorporated within the pore system of MOF 306 for enhancedselectivity of the target analyte. In some cases, metal nanoparticles(e.g., gold, platinum, palladium, copper, and nickel) can be impregnatedin the pore system of MOF 306 to enhance the selectivity of the targetanalyte.

With reference again to FIG. 3, the portion of the fiber optic elementwith the metal organic framework 306 is disposed inside of a flow cell308 equipped with an inlet 310 and an outlet 312. The inlet 310 receivesan air sample from an air source such as one of the locations mentionedabove (e.g., ECS conduit 245, FIG. 2), and can optionally be equippedwith supplemental equipment such as a sampling pump or fan 314 or aheater 316. The core 302 is optically connected on one end to a lightsource 318 (e.g., a laser at a wavelength, e.g., a near-infrared (NIR)laser, that is absorbed by the contaminant but not by other likelycomponents of the gas sample). The light source 318 is connected to thecore 302 through an optical connection 320. The optional connection 320can be any type of optical connection such as a fiber optic cableextension of the fiber optic element in the flow cell 308, or a directconnection of the light source 318 to the fiber optic element in theflow cell 308. The core 302 is optically connected on another end to alight detector 322 through an optical connection 324, which can be thesame or different type of optical connection as the optical connection320. An electronic processing unit 326 is shown connected to read theoutput of the light detector 322, and can be operationally connected(e.g., through wired connections (not shown) or through wirelessconnections) to other system components such as the light source 318,the sampling pump or fan 314 or the heater 316, or to other on-boardsystems and operational structures.

During operation, sampled air is introduced to the flow cell 308 throughthe inlet 310. In the presence of a contaminant 328 such as tricresylphosphate, the contaminant 328 is adsorbed by the MOF 306 to concentratethe contaminant molecules at the interface with the fiber optic core302, where the contaminant molecules provoke a change of the evanescentfield of traveling light in the fiber optic core 302, which in turnimpacts signal intensity as well as spectral changes in the lightreceived by light detector 322. Elution of bound contaminant moleculescan be carried out by exposing the MOF 306 to a heat source such asdirecting air heated by heater 316 (e.g., 80° C.) into the flow cell308. In some embodiments, the electronic processing unit 326 cangenerate a response (or can engage with a master system controller togenerate a response), including but not limited to providing a systemalarm to the presence of the contaminant, reducing a flow rate ofcompressed outside air to the air cycle machine, or increasing arecirculation flow rate in the aircraft pressurized zone.

While the present disclosure has been described in detail in connectionwith only a limited number of embodiments, it should be readilyunderstood that the present disclosure is not limited to such disclosedembodiments. Rather, the present disclosure can be modified toincorporate any number of variations, alterations, substitutions orequivalent arrangements not heretofore described, but which arecommensurate with the spirit and scope of the present disclosure.Additionally, while various embodiments of the present disclosure havebeen described, it is to be understood that aspects of the presentdisclosure may include only some of the described embodiments.Accordingly, the present disclosure is not to be seen as limited by theforegoing description, but is only limited by the scope of the appendedclaims.

What is claimed is:
 1. A method of testing for tricresyl phosphate,comprising: directing light from a light source to a light detector;contacting a test gas with a metal organic framework on an exteriorsurface of an optical guide in communication with the light between thelight source and the light detector; and detecting a change in lightintensity or spectral properties of light received by the light detectorcaused by adsorption of tricresyl phosphate by the metal organicframework.
 2. The method of claim 1, wherein the optical guide comprisesa fiber optic element including a core comprising an optical materialwith a first refractive index, said metal organic framework on a firstexterior surface portion of the core, and a cladding optically coupledto a second exterior surface portion of the core, said claddingcomprising an optical material with a second refractive index lower thanthe first refractive index and configured to reflect light from the coreat an interface between the core and the cladding.
 3. The method ofclaim 2, further comprising a filament, wherein the first exteriorsurface portion is disposed at a central portion along a length of thefilament, and the cladding disposed on each side of the central portionalong the length of the filament.
 4. The method of claim 1, wherein themetal organic framework is configured to adsorb tricresyl phosphate. 5.The method of claim 4, wherein the metal organic framework includes poresizes greater than a molecular kinetic diameter of the tricresylphosphate.
 6. The method of claim 4, wherein the metal organic frameworkincludes functional groups interactive with tricresyl phosphate.
 7. Themethod claim of 1, wherein the metal organic framework includes poreslarger than 1.5 nm.
 8. The method of claim 1, wherein the metal organicframework includes polar functional groups.
 9. The method of claim 1,further comprising a heat source in controllable thermal communicationwith the metal organic framework for regeneration.
 10. The method ofclaim 1, further comprising regenerating the metal organic frameworkwith heated air.
 11. The method of claim 1, further comprising acontroller configured to detect a contaminant based on output from thelight detector, and to generate a response thereto.
 12. The method ofclaim 11, wherein the response is selected from: providing a systemalarm to the presence of the contaminant or activating an aircontaminant removal protocol.